MATERIAL SAFETY DATA SHEET

Company Name: C.R. LAURENCE CO., INC.
Address: 2503 E. VERNON AVE.
City / State / Zip: LOS ANGELES / CA / 90058
US-CHEMTREC Phone(I): (800)424-9300
US-CHEMTREC Phone(II): (703)527-3887
CAN-CANUTEC Phone: (613)996-6666
Vendor Update: 4/2/2015
Date Prepared: 4/2/2015
MSDS Number: TPC16 ;

I. CHEMICAL PRODUCT IDENTIFICATION
Product Name: SURFACE PROTECTOR - UP TO 32 FL.OZ.
HMIS Ratings:
NFPA Ratings:
Flammability: Moderate(2)

Other:                 Recommended use and restrictions
Identified uses
Invisible (nano-scale) water & soil repellent coating for glass, porcelain & ceramics.
Hazard statements: Flammable liquid and vapor.
Precautionary statements
Prevention: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Keep container tightly closed.
Response: Not applicable.
Storage: Store in a well-ventilated place. Keep cool.
Disposal: Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise classified: None known.
II. COMPOSITION, INFORMATION ON INGREDIENTS
Chemical
Ingredients
C.A.S.
Number
% By
Weight
ACGIH TLV
TWA/STEL
OSHA PEL
TWA/STEL
Other
TWA/STEL
LD50 LC50
Ethyl Alcohol
64-17-5
60 - 90

1000 ppm 15 minutes
1900 mg/ml 8 hours
1000 ppm 8 hours

NIOSH REL: 1900 mg/m 10 hours



Notes
Propane-2-ol
67-63-0
1 - 4
200 ppm 8 hours
400 ppm 15 minutes
980 mg/ml 8 hrs
400 ppm 8 hrs

NIOSH REL: 980 mg/mm 10 hrs
400 ppm 10 hrs.
NIOSH REL: 1225 mg/m 15 minutes
500 ppm 15 min


Notes
Diethoxy(dimethyl)silane
78-62-6
0.1 - 1








Notes
Dimethylsilicone Fluid
94363-18-5
1 - 5








Notes
Other: Substance/mixture: Mixture
Other means of identification: Not available.
CAS number/other identifiers
CAS number: Not applicable.
Product code: Not available. Any concentration shown as a range is to protect confidentiality or is due to batch ventilation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed.

III. HAZARDS IDENTIFICATION PRIMARY ROUTE OF ENTRY
Eyes: No known significant effects or critical hazards.

Skin: No known significant effects or critical hazards.

Ingestion: No known significant effects or critical hazards.

Inhalation: No known significant effects or critical hazards.

Medical Conditions Aggravated by Exposure:

Other: Indication of immediate medical attention and special treatment needed. If necessary
Notes to physician: No known significant effects or critical hazards.
Specific treatments: No specific treatment.
Protection of first-aiders: No special measures required.

IV. FIRST AID MEASURES
Eyes: Avoid contact with eyes. If contacted with eyes: In case of contact with eyes, rinse immediately with plenty of water. If irritation persists, get medical attention.

Skin: Skin contact: Avoid contact with skin. If contacted with skin: In case of contact with skin, wash affected areas with soap and water. Get medical attention if symptoms occur.

Ingestion: Do not ingest. If ingested: If swallowed, do not induce vomiting. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if adverse health effects persist or are severe.

Inhalation: Avoid breathing vapor or mist. If inhaled: In case of accident by inhalation, remove victim to fresh air and keep at rest. Move exposed person to fresh air. Get medical attention if adverse health effects persist or are severe.


V. FIRE FIGHTING MEASURES
Flash Point:

Closed cup: 10°C (50°F) [Pensky-Martens.]

Lower Flammability Limit:

Not available

Upper Flammability Limit:

Not available

Extinguishing Agents:

Suitable extinguishing media: Use dry chemical, CO², water spray (fog) or foam.
Unsuitable extinguishing media: Do not use water jet or water-based fire extinguishers.

Unusual Fire or Explosion Hazards:

Specific hazards arising from the chemical: Flammable liquid and vapor.

Fire Fighting Procedures:

Special protective actions for fire-fighters: No special precaution is required
Special protective equipment for fire-fighters: No special protection is required.

Other:

Burning time: Not applicable
Burning rate: Not applicable
Flammability (solid, gas): Not applicable

VI. ACCIDENTAL RELEASE MEASURES
Other:

Personal precautions. protective equipment and emergency procedures
For non-emergency personnel: Avoid breathing vapor or mist. Provide adequate ventilation.
For emergency responders: No special measures are required.
Environmental precautions: Follow all Federal, State and local regulations. Methods and materials for containment and cleaning up
Spill Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

VII. HANDLING AND STORAGE
Other:

Precautions for safe handling
Protective measures:
When using or transferring bulk quantities, put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Store and use away from heat, sparks, open flame or any other ignition source. Do not reuse container.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use.

VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes:

Not required under normal conditions of use.

Skin:

Not required under normal conditions of use.

Respiratory:

Not required under normal conditions of use.

Engineering:

Appropriate engineering controls: No special measures are required
Environmental exposure controls: No special requirements

Other:

Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear
Odor: Ethanol
Boiling Point: 78° C (172.4° F)
pH: 3 [Conc. (% w/w): 1 %]
Solubility in Water: Soluble in water
100 g/l
Vapor Pressure: 4.4 kPa (33 mm Hg) [room temperature]
Vapor Density: >1 [Air = 1]
Physical State: Liquid

Other:

Relative density: 0.792
Partition coefficient (n-octanol/water): Not available
Auto-ignition temperature: Not available
Decomposition temperature: Not available
SADT: Not available
Viscosity: Water

X. STABILITY AND REACTIVITY
Stability:

This product is stable.

Hazardous Decomposition Products:

Hazardous thermal decomposition products
Decomposition products may include the following materials:
carbon dioxide; carbon monoxide; metal oxide/oxides
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Incompatible Products:

Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis

Conditions To Avoid:

Avoid all possible sources of ignition (spark or flame)

Other: Reactivity: No specific test data related to reactivity available for this product or its ingredients
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

XI. TOXICOLOGICAL INFORMATION
Acute Toxicology Data: Product/ingredient name / Result / Species / Dose / Exposure:
Ethyl Alcohol:
LE50 Inhalation Vapor / Rat / 124700 mg/m³ / 4 hours
LD50 Oral / Rat / 7 g/kg / -

Propan-2-ol:
LD50 Dermal / Rabbit / 12800 mg/kg / -

LD50 Oral / Rat / 5000 mg/kg / -

Diethoxy(dimethyl)silane:
LD50 Oral / Rat / 9280 mg/kg / -

Component Toxicology Information: Irritation/Corrosion
Product/ingredient name / Result / Species / Score / Exposure / Observation:
Ethyl Alcohol:
Eyes - Moderate irritant / Rabbit / - / 100 µL / -
Skin - Moderate irritant / Rabbit / - / 24 hours 20 mg / -
Eyes - Mild irritant / Rabbit / - / 24 hours 500 mg / -
Eyes - Moderate irritant / Rabbit / - / 0.066666667 minutes 100 mg / -
Eyes - Severe irritant / Rabbit / - / 500 mg / -
Skin - Mild irritant / Rabbit / - / 400 mg / -

Propan-2-ol:
Eyes - Severe irritant / Rabbit / - / 100 mg / -
Skin - Mild irritant / Rabbit / - / 500 mg / -
Eyes - Moderate irritant / Rabbit / - / 24 hours 100 mg / -
Eyes - Moderate irritant / Rabbit / - / 10 mg / -
Diethoxy(dimethyl)silane:
Eyes - Mild irritant / Rabbit / - / 24 hours 500 mg / -
Skin - Mild irritant / Rabbit / - / 24 hours 500 mg / -

Sensitization: There is no applicable data.
Mutagenicity: There is no applicable data.
Carcinogenicity
Classification
Product/ingredient name / OSHA / IARC / ACGIH / NTP:

Propan-2-ol / None / 3 / A4 Reproductive toxicity: There is no applicable data
Teratogenicity: There is no applicable data
Specific target organ toxicity (single exposure):
Name
Propan-2-ol:
Category / Route of exposure / Target Organs
Category 3 / Not applicable / Narcotic effects Specific target organ toxicity (repeated exposure): There is no applicable data
Aspiration hazard: There is no applicable data.
Information on the likely routes of exposure
Routes of entry anticipated:
Oral
Dermal
Inhalation

Other: Potential acute health effects
Eye contact: No known significant effects or critical hazards
Inhalation: No known significant effects or critical hazards
Skin contact: No known significant effects or critical hazards
Ingestion: No known significant effects or critical hazards

Symptoms related to the physical. chemical and toxicological characteristics
Eye contact: No known significant effects or critical hazards
Inhalation: No known significant effects or critical hazards
Skin contact: No known significant effects or critical hazards
Ingestion: No known significant effects or critical hazards

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure
Potential immediate effects: No known significant effects or critical hazards
Potential delayed effects: : No known significant effects or critical hazards

Long term exposure
Potential immediate effects: No known significant effecls or critical hazards
Potential delayed effects: No known significant effecls or critical hazards

Potential chronic health effects

General: No known significant effects or critical hazards
Carcinogenicity: No known significant effects or critical hazards
Mutagenicity: No known significant effects or critical hazards
Teratogenicity: No known significant effects or critical hazards
Developmental effects: No known significant effects or critical hazards
Fertility effects: No known significant effects or critical hazards

Numerical measures of toxicity
Acute toxicity estimates
Route / ATE value
Oral / 108459.9 mg/kg

XII. ECOLOGICAL INFORMATION
Environmental Fate and Distribution: Bioaccumulative Potential:
Product/ingredient name / LogPow / BCF / Potential
Ethyl Alcohol / ·0.32 / - / low
Propan-2-ol / 0.05 / - / low
Diethoxy(dimethyl)silane / 0.61 / - / low
Mobility in soil
Soil/water partition coefficient (Koc): There is no data available
Other adverse effects: No known significant effects or critical hazards

Ecotoxicity:

Persisitence and Degradation: There is no data available

Other: TOXICITY:
Product/ingredient name / Result / Species / Exposure:

Ethyl Alcohol:
Acute EC50 17.921 mg/l Marine water / Algae - Ulva pertusa / 96 hours
Acute EC50 2000 ug/l Fresh water / Daphnia - Daphnia magna / 48 hours
Acute LC50 25500 µg/l Marine water / Crustaceans - Artemia franchiscana - Larvae / 48 hours
Acute LC50 42000 µg/l Fresh water / Fish - Oncorhynchus mykiss / 4 days
Chronic NOEC 4.995 mg/l Marine water / Algae - Ulva pertusa / 96 hours
Chronic NOEC 0.375 µl/L Fresh water / Fish - Gambusia holbrooki - Larvae / 12 weeks

Propan-2-ol:
Acute LC50 1400000 to 1950000 µg/l Marine water / Crustaceans - Crangon crangon / 48 hours
Acute LC50 1400000 µg/l / Fish - Gambusia affinis / 96 hours

Diethoxy(dimethyl)silane:
Acute EC50 1250 µg/l Fresh water / Daphnia - Daphnia pulex - Neonate / 48 hours

XIII. DISPOSAL CONSIDERATIONS
Disposal Method:

Follow Local & State Laws


XIV. TRANSPORT INFORMATION
Other: Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code : Not available

IMDG: UN Number: UN1993
UN Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.(Ethyl Alcohol, Propan-2-ol)
Transport hazard class(es): 3
Packing group: II
Environmental hazards: No

IATA: UN Number: UN1993
UN Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.(Ethyl Alcohol, Propan-2-ol)
Transport hazard class(es): 3
Packing group: II
Environmental hazards: No

Special precautions for user:
Transport within user's premises:
always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

XV. REGULATORY INFORMATION
TSCA Status:

TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs): Not Listed
Clean Air Act Section 602 Class I Substances Clean Air Act Section 602: Not Listed
Class II Substances DEA list I Chemicals (Precursor Chemicals): Not Listed
DEA list II Chemicals (Essential Chemicals): Not Listed


EPA Sara Title III Chemical Listings:

SARA 302/304
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States Inventory (TSCA 8b): Not determined
Composition/information on ingredients: No products were found
SARA 304 RQ: Not applicable
SARA 311/312
Classification: Fire hazard
Name / % / Fire hazard / Sudden release of pressure / Reactive / Immediate (acute) health hazard / Delayed (chronic) health hazard
Ethyl Alcohol / 60 - 90 / Yes / No / No / Yes / No
Propan-2-ol / 1 - 5 / Yes / No / No / Yes / No
Diethoxy(dimethyl)silane / 0.1 - 1 / Yes / No / No / Yes / No
SARA 313
Product name / CAS number / %
Form R - Reporting requirements:
Propan-2-ol / 67-63-0 / 1 - 5
Supplier notification:
Propan-2-ol / 67-63-0 / 1 - 5
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Supplemental State Compliance Information:



California:

No products were found

Massachusetts:

The following components are listed:
Ethyl Alcohol; Propan-2-ol

New Jersey:

The following components are listed:
Ethyl Alcohol; Propan-2-ol; Diethoxy(dimethyl) silane

Pennsylvania:

The following components are listed:
Ethyl Alcohol; Propan-2-ol

Other: New York: None of the components are listed
International regulations
International lists
Australia inventory (AICS): Not determined
China inventory (IECSC): Not determined
Japan inventory: Not determined
Korea inventory: Not determined
Malaysia Inventory (EHS Register): Not determined
New Zealand Inventory of Chemicals (NZioC): Not determined
Philippines inventory (PICCS): Not determined
Taiwan inventory (CSNN): Not determined
Chemical Weapons Convention List Schedule I Chemicals: Not Listed
Chemical Weapons Convention List Schedule II Chemicals: Not Listed
Chemical Weapons Convention List Schedule III Chemicals: Not Listed

XVI. OTHER INFORMATION

WARRANTY INFORMATION

THIS INFORMATION IS OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION.
NO WARRANTY, EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND
SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD
REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER
THEY ARE APPROPRIATE.